Single-phase and heterophase solid-state chemical kinetics of thermally induced methyl transfer in tetraglycine methyl ester

1997 ◽  
Vol 29 (5) ◽  
pp. 339-348 ◽  
Author(s):  
Evgenyi Yu Shalaev ◽  
Stephen R. Byrn ◽  
George Zografi
Keyword(s):  
Solid State ◽  
Methyl Ester ◽  
Chemical Kinetics ◽  
Single Phase ◽  
Thermally Induced ◽  
Methyl Transfer ◽  
State Chemical ◽  
Kinetics Of

The kinetics of the photo-induced solid-state chemical reaction in Ag/As33S67bilayers and its reaction products

1999 ◽  
Vol 79 (2) ◽  
pp. 223-237 ◽  
Author(s):  
T. Wagner ◽  
E. Márquez ◽  
J. Fernández-Pena ◽  
J. M. González-Leal ◽  
P. J. S. Ewen ◽  
...  
Keyword(s):  
Solid State ◽  
Chemical Reaction ◽  
Reaction Products ◽  
State Chemical ◽  
Solid State Chemical Reaction ◽  
Kinetics Of

On the Methyl-Transfer Reaction in Crystalline Methyl 2-(Methylthio)benzenesulfonate: a Thermally Induced Non-Topochemical Solid-State Reaction

1991 ◽  
Vol 74 (3) ◽  
pp. 662-669 ◽  
Author(s):  
P. Venugopalan ◽  
K. Venkatesan ◽  
J�rg Klausen ◽  
Elisabeth Novotny-Bregger ◽  
Christian Leumann ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Transfer Reaction ◽  
Thermally Induced ◽  
Methyl Transfer

Oxidation kinetics of Pb–Sn alloys

1989 ◽  
Vol 4 (6) ◽  
pp. 1421-1426 ◽  
Author(s):  
R. A. Konetzki ◽  
Y. A. Chang ◽  
V. C. Marcotte
Keyword(s):  
Solid State ◽  
Auger Electron Spectroscopy ◽  
Oxidation Kinetics ◽  
Electron Spectroscopy ◽  
Auger Electron ◽  
Single Phase ◽  
Depth Profiling ◽  
Eutectic Alloys ◽  
Parabolic Oxidation ◽  
Kinetics Of

The solid state oxidation kinetics of Pb–Sn single-phase (2.5 at. % Sn) and eutectic alloys were studied with Auger Electron Spectroscopy combined with sputter depth profiling. The single-phase samples were oxidized in air in the temperature range 22 °C to 250 °C, while the eutectic samples were oxidized from 22 °C to 175 °C. Both alloys oxidize logarithmically between 22 °C and 90 °C and parabolically at temperatures greater than 120 °C. The activation energies for the parabolic oxidation of the single-phase and eutectic alloys are 69.5 and 67.1 ± 8 kJ/mole, respectively.

Kinetics of contracting geometry-type reactions in the solid state: implications from the thermally induced transformation processes of α-oxalic acid dihydrate

2020 ◽  
Vol 22 (35) ◽  
pp. 19560-19572
Author(s):  
Satoki Kodani ◽  
Nobuyoshi Koga
Keyword(s):  
Solid State ◽  
Oxalic Acid ◽  
Current Status ◽  
Thermally Induced ◽  
Oxalic Acid Dihydrate ◽  
Kinetics Of ◽  
Transformation Processes

Thermally induced transformation processes of α-oxalic acid dihydrate reveal the current status of kinetic understanding.

Effects of processing on the solid-state methyl transfer of tetraglycine methyl ester

1997 ◽  
Vol 152 (1) ◽  
pp. 75-88 ◽  
Author(s):  
Evgenyi Yu. Shalaev ◽  
Marina Shalaeva ◽  
Stephen R. Byrn ◽  
George Zografi
Keyword(s):  
Solid State ◽  
Methyl Ester ◽  
Methyl Transfer

White Beam Synchrotron Topographic Studies of the Effects of Localized Stress Fields on the Kinetics of Single Crystal Solid State Reactions.

1988 ◽  
Vol 143 ◽  
Author(s):  
Michael Dudley
Keyword(s):  
Solid State ◽  
Reaction Kinetics ◽  
Local Reaction ◽  
Stress Fields ◽  
Solid State Reactions ◽  
Thermally Induced ◽  
White Beam ◽  
Kinetics Of ◽  
Good Agreement

AbstractWhite Beam Synchrotron Topography has been used to determine the role of localized stress fields in the solid state polymerization of single crystals of the diacetylene PTS. Results indicate that the stress fields due to grown in dislocations can accelerate local reaction kinetics in thermally induced polymerization reactions, although no such effects were previously observable in photolytically or radiolytically induced reactions. Results are analyzed in an analogous fashion to the treatment of the nucleation of solid state phase transformations at dislocations. Good agreement was found between approximate theoretical treatments and experimental observation. The response of the monomer crystal to the inhomogeneous stresses generated as a result of inhomogeneous reaction and the implications regarding local reaction kinetics are discussed in detail.

ChemInform Abstract: The Methyl-Transfer Reaction in Crystalline Methyl 2-(Methylthio) benzenesulfonate: A Thermally Induced Non-Topochemical Solid-State Reaction

ChemInform ◽  
2010 ◽  
Vol 22 (29) ◽  
pp. no-no
Author(s):  
P. VENUGOPALAN ◽  
K. VENKATESAN ◽  
J. KLAUSEN ◽  
E. NOVOTNY-BREGGER ◽  
C. LEUMANN ◽  
...  
Keyword(s):  
Solid State ◽  
Solid State Reaction ◽  
Transfer Reaction ◽  
Thermally Induced ◽  
Methyl Transfer
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